Thermal conductivity is an important property for many iron cast components, and the lack of widely accepted thermal conductivity model for cast iron, especially grey cast iron, motivates the efforts in this research area. The present study contributes to understanding the effects alloy microstructure has on thermal conductivity. A thermal conductivity model for a pearlitic cast iron has been proposed, based on the as-cast alloy composition and microstructural parameters obtained at different solidification rates. According to the model, available parallel heat transfer paths formed by connected graphite flakes across eutectic cells are determined by the space between dendrite arms. The uncertainties both for model inputs and for validation measurements have been estimated. Sensitivity analysis has been conducted to result in better understanding of the model behaviour. The agreement between modelled and measured thermal conductivities has been achieved within 5% on the average for the investigated samples.

Thermal conductivity is an important property for cast components produced from different types of cast iron. Development of a general widely-accepted thermal conductivity model for compacted and lamellar graphite irons poses a research challenge. The present study extends the modeling approach introduced earlier for pearlitic lamellar graphite iron toward compacted graphite iron and ferritic lamellar graphite iron. The proposed thermal conductivity model of the bulk material is based on the alloy microstructure and Si segregation between eutectic cells and non-cell regions, at the main assumption that the heat paths in the eutectic cells are formed by connected graphite phases surrounded by ferrite phases. The overall thermal resistance of these heat paths is determined by the hydraulic diameter of the interdendritic region. The uncertainties both for the modeled and for experimentally derived thermal conductivities have been estimated. The importance of considering the Si segregation in the model has been discussed. For the investigated samples, the agreement between modeled and measured thermal conductivities has been achieved within 4% on the average, at the same value of the single fitting parameter found for pearlitic, pearlitic–ferritic lamellar, and compacted graphite iron alloys. The results contribute to the understanding of the material microstructure effects on the cast iron thermal conductivity.

In this study four compacted graphite irons (CGIs) and one grey cast iron (FGI) were produced and tested in the laboratory. The molybdenum content of the four CGI grades was varied between 0 and 1··01 wt-%. The purpose of the investigations was to examine the effect of the different molybdenum contents of the CGI on the thermomechanical fatigue (TMF) behaviour. The TMF tests were performed by cycling a constrained specimen between 110 and 600°C. For every material three tests were performed on specimens machined from a ∅20 mm cylinder. Other tests were performed on specimens machined from ∅55 mm and ∅85 mm cylinders respectively. The tests showed that additions of molybdenum improved the fatigue resistance of CGI. It was observed that additions of molybdenum refined the pearlite and that the specimens with a finer metallic matrix had a higher TMF resistance.

In a previous study, the thermomechanical fatigue resistance of four compacted graphite irons (CGIs) and one grey cast iron was investigated. The molybdenum content of the four CGIs varied between 0 and 1.01 wt-%. It was observed that during thermal cycling, the maximum value of the compressive stress continuously decreased while the value of the maximum tensile stress continuously increased. The continuous decrease in compressive stresses showed that stress relaxation occurs at elevated temperatures during thermal cycling. The goal of the present investigation was to investigate the phenomenon of stress relaxation at elevated temperatures. The tests were performed at 350 and 600°C respectively. The results of the stress relaxation tests performed at 600°C showed the same trend observed at thermomechanical fatigue testing. The tests showed that additions of molybdenum improved the fatigue resistance of CGI by lowering the stress relaxation rate.

Computer simulation of casting becomes a valuable tool for developing advanced materials and casting components. Recent investigations and validation work on simulated cast components reveal the necessity of reliable analyses methods to determine solidification behaviour and to extract parameters for kinetic models to use at simulation of complex cast iron materials.

The paper will present an inverse modelling method for determination of eutectic growth. The method include an experimental part proper to investigate simultaneously the solidification at three different cooling rates while the cast material has the same metallurgical origin, and a computational part for calculation of grow kinetics. Validation of the inverse method is made together with simulation. The inverse modelling of eutectic growth in grey iron indicates that chemical composition, type and amount of inoculants and cooling condition are strongly influencing the eutectic growth condition and gives different eutectic growth coefficients. By invoking a generalized KJMA* equation, the shape of the growing eutectic interface can be predicted. Deviation from perfectly spherical growth in real solidification cases is the source of variation of eutectic growth coefficients. The results of the inverse model are valuable to simulate differences in solidification behaviour in differently treated grey iron melts.

* KJMA is the abbreviation of the name of the famous scientists Kolmogorow, Johnson, Mehl and Avrami who developed and applied the equation.

A major user of cast components is the automotive industry, where the functionality of the components is related to environmental demands. Internal combustion engines are constantly being improved to emit less pollution. A vital part in this development is to increase the material properties of engine components during their life cycle. In particular, cylinder heads, cylinder blocks and piston rings for diesel engine are produced in grey cast iron. Cast iron is expected to be in use far into the foreseeable future, due to favourable properties and low production costs. This work has been devoted to study microstructure formation, the tensile properties of cast iron and to some extent defect formation.

The microstructure develops during solidification and solid state transformations. An inverse thermal analysis method was developed to study the kinetics of the microstructure formation. The inverse thermal analysis used, the Fourier method, analyses the cooling curves of two thermocouples to study the solidification or transformation. To decrease experimental errors, simulations have been done and the cooling curves were analysed. The best results were obtained when the thermocouples were placed close to each other.

With the help of the thermal analysis a time dependent and fading nucleation law of the eutectic cells was found to fit the experimental results best. The experiments were made by multiple thermal analyses, and six different types of inoculants were investigated. The eutectic growth behaviour during solidification was evaluated with inverse thermal analysis, and it was found that commercial inoculants not only affect the eutectic nucleation but they also control the eutectic growth rate.

Models of densities and volume changes are an integral part of a microstructure simulation of cast irons. These models are important for the inverse thermal analysis and an understanding of the porosity and expansion penetration in cast iron.

The tensile strength of grey cast iron has been discussed by examining the fracture mechanism of the material at failure. The ultimate tensile strength is a result of the intimate collaboration between the graphite flake and the primary phases. Several parameters, including the graphite morphology, carbon content, inoculation and cooling conditions influence the ultimate tensile strength by offseting the equilibrium between the major constituents, the graphite flakes embedded in the primary metallic matrix. A model to predict the ultimate tensile strength is developed based on the interpretation of the stress intensity behaviour in a eutectic cell.

The models developed for nucleation, eutectic growth and prediction of tensile strength were introduced into a casting simulation program. Mould filling, solidificauon, microstructure development and tensile strength of a complex. shaped cylinder head were simulated.

Gray cast iron has been investigated with respect to surface turbulence during mould filling. Different levels of flow velocities have been provoked in a vertically parted sand mould. The thermal resistant transparent front side of the mould permitted the observation of the flow pattern due to high speed camera registration. The registered frames including the liquid surface were investigated using image analyses. The results show good correlation between the average flow velocity and the liquid iron surface extension. Consequently it has been demonstrated that an increased absorption of hydrogen and nitrogen during mould filling is dependent on the level of liquid surface turbulence.

The goal of this book is to present for readers the articles from the 11th International Symposium on the Science and Processing of Cast Iron that was held in September 2017 in Jönköping, Sweden. The content of the book reflects the state of the art, research and development tendencies of cast iron as the main engineering cast material also in the 21st century.

Purpose - The purpose of this paper is to obtain a finite difference method (FDM) solution using control volume for heat transport by conduction and the heat absorption by the enthalpy model in the sand mixture used in casting manufacturing processes. A mixture of sand and different chemicals (binders) is used as moulding materials in the casting processes. The presence of various compounds in the system improve the complexity of the heat transport due to the heat absorption as the binders are decomposing and transformed into gaseous products due to significant heat shock. Design/methodology/approach - The geometrical domain were defined in a 1D polar coordinate system and adapted for numerical simulation according to the control volume-based FDM. The simulation results were validated by comparison to the temperature measurements under laboratory conditions as the sand mould mixture was heated by interacting with a liquid alloy. Findings - Results of validation and simulation methods were about high correspondence, the numerical method presented in this paper is accurate and has significant potential in the simulation of casting processes. Originality/value - Both numerical solution (definition of geometrical domain in 1D polar coordinate system) and verification method presented in this paper are state-of-the-art in their kinds and present high scientific value especially regarding to the topic of numerical modelling of heat flow and foundry technology.

Defect formation like gas- and shrinkage porosity at cast iron component production is related to the content of gaseous elements in the liquid metal. The present work investigate the solubility of hydrogen and nitrogen in liquid iron aimed for production of lamellar and compacted graphite cast iron. The used methods and instruments are a combination of commercial measuring devices and novel experimental assemblies for measuring solubility of hydrogen and nitrogen during melting and mold filling of a complex shaped cast component. The obtained results reveal the role of the charge material and the mold filling on the solubility of the investigated elements. 

Shrinkage porosity formation mechanisms at production of cast iron components is particularly complex and became more and more difficult to understand since the shape casting complexity have been increased more and more in advanced component applications. The present work intends to summarize the state of the art in understanding the shrinkage porosity formation mechanism of cast iron based on a series of key publications, MSc and PhD theses performed in collaboration between cast iron component users, producers and researchers.

Cast iron is one of the oldest technical alloys used for creating objects. Foundrymen from the very beginning of casting was fighting to avoid casting defects. In the beginning a successfully performed casting was associated with witchcraft. Cast component producers suffer yearly substantial expenses due to rejecting or repairing castings. The present work will summarize research efforts to understand formation mechanisms of defects, performed in collaboration with Swedish foundries during the last years. The presented work will focus on defects, specific casting of gray iron components. Studied defects are gas porosity, shrinkage porosity and metal expansion penetration. Novell experimental set up has been developed or existing methods has been improved to study defect formation mechanisms. Today we can realize that casting without defects are possible only by approaching the defect formation mechanism with multidisciplinary science.

Lamellar graphite cast iron was investigated with carbon equivalents varied between CE = 3.4 and 4.26, cast at various cooling rates between 0.195 and 3.5 °C s−1 covering the limits used for technical applications in the production of complex-shaped lamellar graphite cast iron. Registered cooling curves displaced in two positions in the casting were used to predict the solidification and microstructure formation mechanisms. The predicted volume fraction of primary austenite was compared with the fraction of primary austenite measured on colour micrographs with the help of image analyses. A good correlation has been obtained for medium and slow cooling conditions, while a less good correlation at fast cooling condition was attributed to the used protective environment to preserve thermocouples. The observed fraction and the predicted fraction of primary austenite were in good correlation and followed a consequent variation dependent on the carbon equivalent. Furthermore, the quality of the prediction was dependent on the used numerical algorithm involving cooling information from either one or two thermocouples.

Primary austenite has been underestimated in general when the theories of nucleation, solidification, microstructure formation and mechanical properties was established for cast iron and particularly for lamellar cast iron. After extensive use of colour etching during the last two decades it has been found that primary austenite dendrites can be characterized using general morphology parameters like those used for other technical cast alloys with dendritic structure. The present work aims to investigate the primary austenite morphology of as-cast samples of a hypoeutectic lamellar cast iron produced with different cooling rates. Morphological parameters as the area fraction primary austenite, the secondary dendrite arm spacing, the dendrite envelope surface, the coarseness of the primary dendrite expressed as the relation between the volume of the dendrite and its envelope surface and the coarseness of the interdendritic space also known as the hydraulic diameter are measured. Furthermore the role of the size of investigation area is revealed be sequential investigation. A strong relation between all measured morphological parameters and the solidification time have been established excepting the volume fraction of primary austenite which is constant for all cooling conditions.

Primary austenite has been underestimated in general when the theories of nucleation, solidification, microstructure formation and mechanical properties were established for cast iron and particularly for lamellar cast iron. The present work aims to investigate the primary austenite morphology of as cast samples of a hypoeutectic lamellar cast iron produced with different cooling rates. Morphological parameters as the area fraction primary austenite, the secondary dendrite arm spacing, the dendrite envelope surface, the coarseness of the primary dendrite expressed as the relation between the volume of the dendrite and its envelope surface and the coarseness of the interdendritic space also known as the hydraulic diameter are measured. Furthermore, the role of the size of the investigation area is revealed to be sequential investigation. A strong relation between all measured morphological parameters and the solidification time has been established, except the volume fraction of primary austenite, which is constant for all cooling conditions.

The fracture mechanism of gray cast iron was investigated on tension loaded samples produced under different conditions. The parameters studied included the graphite morphology, the carbon content, the inoculation and the cooling condition. The observations made reveal the role of the microstructure on crack propagation. The cracks were found to always propagate parallel with the graphite flakes. The interaction between the metallic matrix precipitated as primary austenite and graphite has been interpreted by a simplified model of the austenite reinforced eutectic cell. The geometrical transcription gave a standard crack component configuration with known mathematical solution. The microstructure observed in the experiments has been analysed by means of a novel interpretation. The fictitious stress intensity at yield and the fictitious maximum stress intensity at failure are strongly related to the relative shape of the eutectic cell and the fraction primary austenite. A different slope is observed for the material cooled at high rate when the precipitation of primary carbide reduces the stress intensity. The observed relations indicate that the tensile strength of the grey cast iron is the result of the collaboration between the toughness of the metallic matrix precipitated as primary austenite and the brittleness of the graphite phase. The shape and distribution of the primary austenite and graphite can be influenced by chemical composition, by inoculation or by the cooling condition, but they will maintain equilibrium with respect to the stress intensity.

Dynamic coarsening of austenite dendrite in lamellar cast iron has been studied for a hypoeutectic alloy. The common morphological parameter to characterize dynamic coarsening, secondary dendrite arm space has been replaced by the Modulus of primary dendrite (MPD) and the Hydraulic diameter of the interdendritic space (DHydIP) to interpret the dynamic coarsening with respect to the local solidification time. The obtained results demonstrate the coarsening process of both the solid and liquid phase. The interdendritic space is increasing as the contact time between the solid and liquid phase increases. The ratio between the DHydIP/MPD is strongly dependent on the precipitated fraction primary austenite indicating clearly the morphology variation during coarsening. The interrupted solidification method demonstrate that the observed coarsening process is not only a combination of the increasing fraction precipitated solid phase and the rearrangement of the solid - liquid interphase curvature but the volume change due to density variation is also contribute to the coarsening process.

Although lamellar cast iron has been used in advanced applications for about 20 years, our knowledge about the mechanisms affecting microstructure and defect formation is relatively limited. The present paper summarises some solidification-related phenomena from a series of recently published peer-reviewed papers and scientific theses and suggests a mechanism of defect formation which is dependent on the shape of the solidifying casting geometry. When shrinkage porosity or metal expansion penetration occurs, evidence of material transport in the intergranular zone of primary equiaxed austenite grains in the casting and in the intergranular regions between the sand grains in the mould material is seen. Material transport occurs across the casting-mould interface, where the existence of or the permeability of the primary columnar zone determines if material transport can take place.

A method of analyzing a phase transformation process of a material comprises providing a spherical sample of the material, measuring and recording a first data series of core temperature at the sample's center of gravity, measuring and recording a respective second data series of temperature at the sample's periphery, measuring and recording a respective third data series of radial displacements at the sample's periphery, and calculating a change in pressure in the sample at a plurality of points in time based on first, second and third said data series.

This paper describes and validates a methodology for implementation of full-scale sand-casting simulation in a general-purpose finite element software, including mold filling, heat transport, solidification kinetics, chemical microsegregation and prediction of microstructure and material properties. The solidification model, customized for gray cast iron, includes novel methods for handling interaction between parallel dendritic and eutectic solidification modes and its impact of their interaction on the final microstructure. The validation involves a previously published gray iron casting experiment and involves comparison of simulated and experimental cooling curves, microstructure parameters and tensile strength. We believe that this is valuable to researchers and engineers seeking to improve the state of the art of casting simulation tools.