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Template synthesis of Au/Co multilayered nanowires by electrochemical deposition
Jönköping University, School of Engineering, JTH. Research area Materials and manufacturing - Surface technology. Jönköping University, School of Engineering, JTH. Research area Robust Embedded Systems.ORCID iD: 0000-0002-7095-1907
2002 (English)In: Advanced Functional Materials, ISSN 1616-301X, E-ISSN 1616-3028, Vol. 12, no 11-12, p. 766-772Article in journal (Refereed) Published
Abstract [en]

The electrochemical deposition of Au/Co multilayers into 20 μm-thick ion track etched polycarbonate membranes with pore diameters of 110–150 nm was studied in a single electrolyte containing cobalt sulfate, gold cyanide, and citric acid. Cyclic voltammetry, chronoamperometry, and pulse-potential experiments were used to determine the deposition conditions for pure Au and 98 wt.-% Co layers. The Co-rich metallic nanowires were deposited at –1100 mV and the Au nanowires at –490 mV vs. Ag/AgCl. Under open-circuit conditions an Au-displacement reaction occurred. Open-circuit conditions were applied in combination with a steep ramp between the Co and Au potential pulses to avoid the otherwise severe Co dissolution when the potential was switched to less negative values. Scanning and transmission electron microscopy of the deposited multilayered nanowires revealed dense and well-defined layer interfaces. X-ray diffraction investigations of 20 μm long Au and Co nanowires showed that the Au deposits exhibit a face-centered cubic (fcc) <111> texture, while the Co deposits exhibit a hexagonal close-packed (hcp) (002) structure. The magnetic measurements of 12 nm Co/4 nm Au nanowires for fields applied parallel and perpendicular to the film plane indicate a low remnant magnetization.

Place, publisher, year, edition, pages
2002. Vol. 12, no 11-12, p. 766-772
Keywords [en]
Electrochemical fabrication, Nanostructures, multilayers, Nanowires, metal, Au, Co, Template-directed synthesis
National Category
Manufacturing, Surface and Joining Technology
Identifiers
URN: urn:nbn:se:hj:diva-6192DOI: 10.1002/adfm.200290005OAI: oai:DiVA.org:hj-6192DiVA, id: diva2:37012
Note
Forskningsområdet Robusta inbyggda system bytte namn till Forskningsmiljö Material och tillverkning – Ytteknik 2011-01-01 Research area Robust Embedded Systems changed its name to Research area Materials and manufacturing - Surface technology 01-01-2011 Available from: 2007-08-03 Created: 2007-08-03 Last updated: 2018-09-19Bibliographically approved

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Leisner, Peter

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JTH. Research area Materials and manufacturing - Surface technologyJTH. Research area Robust Embedded Systems
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