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Influence of Melting Process on Hydrogen and Nitrogen Content in Gray Iron
Jönköping University, School of Engineering, JTH, Mechanical Engineering. Jönköping University, School of Engineering, JTH. Research area Component Technology.
Jönköping University, School of Engineering, JTH, Mechanical Engineering. Jönköping University, School of Engineering, JTH. Research area Component Technology.
Jönköping University, School of Engineering, JTH, Mechanical Engineering. Jönköping University, School of Engineering, JTH. Research area Component Technology.
2007 (English)In: Transactions of the American Foundry Society: One Hundred Eleventh Annual Metalcasting Congress May 15 - 18, 2007, Schaumburg, Ill.: American Foundry Society , 2007, Vol. 115, p. 617-623Conference paper, Published paper (Refereed)
Abstract [en]

High concentrations of hydrogen and nitrogen in molten gray iron increase the risk of porosity in castings. Therefore, equilibrium variations of these gases at different stages in the process chain from melting to casting have been mapped. Both hydrogen and nitrogen content are affected by the melting method. The amount of hydrogen is also sensitive to the dwell-time in ladles and holding furnaces. The total amount of nitrogen, i.e. bonded and dissolved nitrogen, is not significantly affected by the temperature, while the hydrogen content is indirectly affected because of the relationship between dwell-time and temperature.

Place, publisher, year, edition, pages
Schaumburg, Ill.: American Foundry Society , 2007. Vol. 115, p. 617-623
Series
American Foundry Society. Transactions, ISSN 0065-8375 ; 115
Keywords [en]
Gray iron, Porosity, Castings, Gas content
Identifiers
URN: urn:nbn:se:hj:diva-4778ISBN: 9780874333381 (print)OAI: oai:DiVA.org:hj-4778DiVA, id: diva2:35598
Available from: 2007-12-07 Created: 2007-12-07 Last updated: 2010-02-10Bibliographically approved
In thesis
1. Defect Formation during Solidification in Grey Iron Castings
Open this publication in new window or tab >>Defect Formation during Solidification in Grey Iron Castings
2009 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

The presence of defects is of major concern in the production of grey iron castings. Some defects are merely an aesthetic problem while others can be detrimental for the performance of the component. Among the several possible defects, shrinkage porosity is one of the more challenging to understand and avoid. This type of defect can penetrate through the casting as a three-dimensional network. The purpose of this work has been to develop knowledge and understanding about the foundry process in order to increase product quality by eliminating or at least minimising the presence of shrinkage porosity in the production of vital engine components. This was done by developing fundamental knowledge concerning factors known to influence the presence of shrinkage porosity.

Initially, an investigation was carried out in order to characterize shrinkage porosity commonly occurring in cylinder heads. Factors found to be important and contributing to the formation of shrinkage porosity were identified. It was found that this type of defect is formed at hot spots that have migrated during solidification. Knowledge of the migrating hot spot was used as a design criterion in the development of a geometry with the purpose of deliberately generating porosity. Based on this geometry a mechanism for the formation of this type of shrinkage porosity was proposed.

The formation of shrinkage porosity depends on gases dissolved in the melt. In this work, their levels and variations in the melting process were investigated. It was shown how the solubility of oxygen depends on the temperature but not on the method used to produce the iron. On the other hand, the total amount of oxygen depends on the process but not on temperature. The discussion about gases also included hydrogen and nitrogen.

The solidification of grey cast iron is complex. It is during the solidification that not only the final properties of the component but also the conditions for defect formation are established. Shrinkage porosity is formed due to volumetric changes followed by an inability to supply material to the contracting areas. The solidification of grey iron starts with nucleation and growth of the primary austenite followed by nucleation of eutectic cells. It was found that the microstructural constituents are interconnected. The importance of the macrostructure was also discussed and it was shown that shrinkage porosity can be found not only between eutectic cells but also between equiaxed crystals.

Place, publisher, year, edition, pages
Göteborg: Chalmers University of Technology, 2009
Series
Doktorsavhandlingar vid Chalmers tekniska högskola. Ny serie, ISSN 0346-718X; nr 2935, ISSN 0346-718X ; 2935
Keywords
Shrinkage Porosity, Grey Iron, Solidification, Nucleation, Primary Austenite, DAAS, Eutectic Cells, Microstructure, Macrostructure, Hot Spot, Oxygen, Hydrogen
National Category
Materials Engineering
Identifiers
urn:nbn:se:hj:diva-11606 (URN)978-91-7385-254-8 (ISBN)
Public defence
2009-05-12, E1405, JTH, Gjuterigatan 5, Jönköping, 10:00 (English)
Opponent
Supervisors
Note
Thesis from the Department of Materials and Manufacturing Technology, Chalmers University of Technology AND the Department of Mechanical Engineering, Materials and Manufacturing – Castings, School of Engineering, Jönköping University Available from: 2010-02-10 Created: 2010-02-10 Last updated: 2010-02-10Bibliographically approved

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Orlenius, JessicaElmquist, LennartDiószegi, Attila

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