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Role of Iron-Rich Phases and Porosity on the Ductility of Rheocast Al-Mg-Si-Alloys
Jönköping University, School of Engineering, JTH, Materials and Manufacturing.ORCID iD: 0000-0002-0431-4352
Royal Institute of Technology, Department of Materials science, Stockholm, 1044, Sweden.
Jönköping University, School of Engineering, JTH, Materials and Manufacturing.ORCID iD: 0000-0002-3184-7592
Jönköping University, School of Engineering, JTH, Materials and Manufacturing.ORCID iD: 0000-0002-0101-0062
2022 (English)In: Solid State Phenomena / [ed] J. Li & A. Rassili, Trans Tech Publications, 2022, Vol. 327, p. 65-70Chapter in book (Refereed)
Abstract [en]

Treatment of the slurry is important during RheoMetalTM casting. In this work, semi-solid slurries were prepared under different stirring intensities, using two types of stirrers: a naked rod (for regular stirring) and a rod with two blades (for intensive stirring). Tensile tests were performed, investigating fracture surfaces, as well as metallographic samples. The results show that intensive stirring produces castings with finer primary particles and a more homogeneous microstructure. On the other hand, more faceted Fe-rich phases are found along the α-Al grains boundary, due to the dissolution of Fe from the stirrers. Moreover, for intensive stirring castings, the porosity found on the fracture surfaces are smaller, while more second (intermetallic) phases, especially Fe-rich phases, are observed. Consequently, the castings with intensive stirring show worse ductility. Finally, a quantitative analysis was made regarding ductility, affected both by porosity and the presence of Fe-rich phases.

Place, publisher, year, edition, pages
Trans Tech Publications, 2022. Vol. 327, p. 65-70
Series
Solid State Phenomena, ISSN 0377-6883, E-ISSN 1662-9779 ; 327
Keywords [en]
Elongation, Fe-rich intermetallic, Intensive stirring, Porosity, Segregation, Semi-solid casting
National Category
Materials Engineering
Identifiers
URN: urn:nbn:se:hj:diva-56184DOI: 10.4028/www.scientific.net/SSP.327.65Scopus ID: 2-s2.0-85127198596ISBN: 9783035717792 (electronic)OAI: oai:DiVA.org:hj-56184DiVA, id: diva2:1651481
Conference
16th International Conference on Semi-Solid Processing of Alloys and Composites, S2P 2021
Funder
Vinnova, 2018-02831Available from: 2022-04-12 Created: 2022-04-12 Last updated: 2024-01-09Bibliographically approved
In thesis
1. Mechanical Properties of Semi-Solid Al Castings: Role of Stirring
Open this publication in new window or tab >>Mechanical Properties of Semi-Solid Al Castings: Role of Stirring
2022 (English)Licentiate thesis, comprehensive summary (Other academic)
Abstract [en]

Semi-solid metal (SSM) casting has been widely used in automotive industries to reduce the weight. In RheoMetalTM process which is one of the variations of SSM, the slurry fabrication can be finished within 30 second and can the slurry making process can be integrated into a high pressure die casting (HPDC) route without significant adjustments, making the process a promising alternative for industrial application. However, the application of SSM is still limited due to the semi-solid deformation-induced casting defects, such as macrosegregation and large pores. Due to the short stirring duration, the inefficient stirring is the leading cause of defects formation. Another critical issue in the RheoMetalTM process is the oxidation during the stirring process, which results in the increase of oxides in the castings, reducing the mechanical properties.

This study aims to investigate the ductility and the fatigue performance of SSM castings. The main focuses were on the role of the stirring and oxides. The quenched slurry was analyzed to evaluate the effect of the stirring on the particle distribution in the slurry, and its effect on the formation of pores and segregation was discussed. To investigate the oxidation during the slurry making process, two alloys with different Mg content were cast. Scanning electron microscopy (JEOL JSM-7001F SEM) equipped with Energy-dispersive X-ray spectroscopy (EDS) was used to identify the oxides on the fracture surface. Tensile test and fatigue test accompanied with direct current potential drop (DCPD) were performed to investigate the ductility and fatigue performance, respectively.

The results suggest that the intensive stirring can avoid the formation of the large clusters, making the particle distribution homogeneous in the slurry. The Mg contents determined the types of the oxides formed in the slurry making process. For alloys with sufficient Mg, the oxides would be MgAl2O4, which exist as small films with numerous cracks, while a large oxides film will be formed in the case of low Mg content.

The combined influence of porosity and oxides was concluded. In the 42000 alloy, because of the low Mg content, the ductility was dominated by the large oxide films. In contrast, in the Magsimal 59 alloy, the presence of small oxides (less than 0.2 mm in majority) leads to the influence of oxides on the elongation negligible. However, a good correlation was obtained between the largest pores and ductility.

The fatigue test shows that the surface liquid segregation (SLS) determined the fatigue strength under cyclic bend loading, due to its higher hardness. The effect of the inner pores on the fatigue performance was negligible, as the maximum stress was applied on the surface.

Abstract [sv]

Halvsolid metall (SSM) gjutning har använts i stor utsträckning inom bilindustrin för att minska vikten. I RheoMetalTM-processen, som är en av varianterna av SSM, kan slurrytillverkningen avslutas inom 30 sekunder och kan slurryframställningsprocessen integreras i en högtrycksgjutningsrutt (HPDC) utan betydande justeringar, vilket gör processen till ett lovande alternativ för industriell tillämpning. Tillämpningen av SSM är dock fortfarande begränsad på grund av de halvfasta deformationsinducerade gjutdefekterna, såsom makrosegregering och stora porer. På grund av den korta omrörningstiden är den ineffektiva omrörningen den främsta orsaken till att defekter bildas. En annan kritisk fråga i RheoMetalTM-processen är oxidationen under omrörningsprocessen, vilket resulterar i ökningen av oxider i gjutgodset, vilket minskar de mekaniska egenskaperna.

Denna studie syftar till att undersöka duktiliteten och utmattningsprestandan hos SSM-gjutgods. Huvudfokus var på omrörningens och oxidernas roll. Den kylda uppslamningen analyserades för att utvärdera effekten av omrörningen på partikelfördelningen i uppslamningen, och dess effekt på bildandet av porer och segregation diskuterades. För att undersöka oxidationen under slurrytillverkningsprocessen göts två legeringar med olika Mg-halt. Svepelektronmikroskopi (JEOL JSM-7001F SEM) utrustad med energidispersiv röntgenspektroskopi (EDS) användes för att identifiera oxiderna på brottytan. Dragtest och utmattningstest tillsammans med likströmspotentialfall (DCPD) utfördes för att undersöka duktiliteten respektive utmattningsprestandan.

Resultaten tyder på att den intensiva omrörningen kan undvika bildningen av de stora klustren, vilket gör partikelfördelningen homogen i slammet. Mg-innehållet bestämde vilka typer av oxider som bildades i slurrytillverkningsprocessen. För legeringar med tillräckligt med Mg skulle oxiderna vara MgAl2O4, som finns som små filmer med många sprickor, medan en stor oxidfilm kommer att bildas vid låg Mg-halt.

Den kombinerade inverkan av porositet och oxider konstaterades. I 42000-legeringen, på grund av det låga Mg-innehållet, dominerades duktiliteten av de stora oxidfilmerna. Däremot, i Magsimal 59-legeringen, leder närvaron av små oxider (mindre än 0,2 mm i majoritet) till att oxidernas inverkan på förlängningen är försumbar. En god korrelation erhölls dock mellan de största porerna och duktiliteten.

Utmattningstestet visar att ytvätskesegregeringen (SLS) bestämde utmattningshållfastheten under cyklisk böjbelastning, på grund av dess högre hårdhet. Effekten av de inre porerna på utmattningsprestandan var försumbar, eftersom den maximala belastningen applicerades på ytan.

Place, publisher, year, edition, pages
Jönköping: Jönköping University, School of Engineering, 2022. p. 49
Series
JTH Dissertation Series ; 069
Keywords
Rheometal™ process; aluminium alloys; stirring; segregation; porosity; oxides; ductility; fatigue performance
National Category
Materials Engineering
Identifiers
urn:nbn:se:hj:diva-56203 (URN)978-91-87289-75-0 (ISBN)
Presentation
2022-05-12, Tekniska Högskolan, Jönköping, 13:00 (Swedish)
Opponent
Supervisors
Available from: 2022-04-14 Created: 2022-04-14 Last updated: 2023-11-22Bibliographically approved
2. Mechanical properties of semi-solid Al castings: Role of stirring
Open this publication in new window or tab >>Mechanical properties of semi-solid Al castings: Role of stirring
2023 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

Aluminum castings have been widely used in the automotive industry to reduce the vehicle's weight. However, the existence of casting defects significantly limits its application. The most common and detrimental defects in aluminum castings are porosity and oxides. The formation of the pores comes from the solute hydrogen and volumetric reduction during the solidification process, resulting in the gas and shrinkage pores, respectively. The oxides can be introduced by either the operation during the process or the originally existing oxides in the melt. To reduce these defects, optimizing the casting process and controlling the melt quality is essential.

In this work, the Semisolid Metal (SSM) process was used as it can significantly reduce the formation of shrinkage pores. The main focuses were on the influence of stirring intensity on the formation of casting defects and, thus, the resultant mechanical properties. In addition, to control the original melt quality, particularly the amount of oxides, efforts were made to develop proper methods for the melt quality assessment.

The results show that the slurry-making process, mainly through stirring intensity, can affect the casting defects significantly. On the one hand, the increasing stirring intensity can distribute the primary Al particles more homogeneously, reducing the pores in terms of size and number by increasing the permeability during the solidification process. On the other hand, the increasing stirring intensity can affect the size of oxides differently, depending on the composition, for instance, the Mg content.

For the alloys with sufficient Mg, the oxides would be MgAl2O4, which are small films with numerous cracks. Under intensive stirring, the oxides can break down into small oxide particles. As a result, intensive stirring can improve ductility by reducing the formation of big pores. However, the oxides would mainly be Al2O3 films for alloys with low Mg content. In this case, the current stirring intensity is insufficient to break the oxide films. Instead, the increased stirring has introduced more oxide films into the melt. Consequently, in the casting with intensive stirring, the increasing oxide films dominated the ductility rather than the reduced porosity.

The SSM castings exhibit better bending fatigue properties than the casting using the traditional high-pressure die casting (HPDC) process. This improvement is mainly due to the formation of the harder surface liquid segregation (SLS) layer on the SSM casting surface. Furthermore, compared with the standard SSM process, the castings using intensive stirring (hereinafter referred to as the modified SSM process) show similar but more reliable fatigue properties. This reliable fatigue property can be attributed to eliminating the big internal pores through intensive stirring, which results in local stress concentration and significantly reduces fatigue performance. Besides, due to the gradient stress distribution in the bending loading, the surface defects play a significant role in the fatigue properties. With the increase of the specimens’ thickness, the failure mechanisms changed.

The shrinkage pores in the reduced pressure test (RPT) test play a significant role in the accuracy of melt quality assessment. A good correlation between the bifilm index (BI)/ density index (DI) and hydrogen content is observed for the RPT samples without significant shrinkage pores. In addition, the correlation between the BI and elongation is also strongly affected by the clusters of shrinkage pores due to the conflict between the definition of the BI and the influence of clusters of shrinkage pores on the ductility. Based on this, we proposed an optimized BI where the clusters of shrinkage pores were treated as single pores, increasing the reliability of the correlation between the BI and elongation. 

Abstract [sv]

Aluminiumgjutgods har använts i stor utsträckning inom bilindustrin för att minska fordonets vikt. Förekomsten av gjutningsdefekter begränsar emellertid dess tillämpning avsevärt. De vanligaste och mest skadliga defekterna i aluminiumgjutgods är porositet och oxider. Bildandet av porerna kommer från löst väte och volymetrisk reduktion under stelningsprocessen, vilket resulterar i att gasporerna respektive krymperporerna. Oxiderna kan införas antingen genom operationen under processen eller de ursprungligen existerande oxiderna i smältan. För att minska mängden av dessa defekter måste gjutningsprocessen optimeras och smältkvaliteten måste kontrolleras kritiskt samtidigt.

I detta arbete användes Semisolid Metal (SSM)-processen. Fokus ligger på inverkan av omrörningsintensiteten på bildandet av gjutdefekter och de resulterande mekaniska egenskaperna. För att kontrollera den ursprungliga smältkvaliteten, särskilt mängden oxider, gjordes ansträngningar för att utveckla lämpliga metoder för bedömning av smältkvaliteten.

Resultaten visar att slurrytillverkningsprocessen påverkar gjutdefekterna avsevärt. Å ena sidan kan den ökande omrörningsintensiteten fördela de primära Al-partiklarna mer homogent, vilket minskar porerna vad gäller storlek och antal genom att öka permeabiliteten under stelningsprocessen. Å andra sidan kan den ökande omrörningsintensiteten påverka storleken på oxider olika beroende på sammansättningen, till exempel Mg-halten.

För legeringar med tillräckligt med Mg skulle oxiderna vara MgAl2O4, som existerar som små filmer med många sprickor. Under intensiv omrörning kan oxiderna brytas ner till små oxidpartiklar. Som ett resultat kan intensiv omrörning förbättra duktiliteten genom att minska bildningen av stora porer. För legeringarna med lågt Mg-innehåll är emellertid oxiderna huvudsakligen Al2O3-filmer. I detta fall är den aktuella omrörningsintensiteten inte tillräcklig för att bryta oxidfilmerna, utan fler oxidfilmer kan införas i smältan. Följaktligen, i gjutningen med intensiv omrörning, dominerades duktiliteten av de ökande oxidfilmerna snarare än den minskade porositeten.

På grund av bildandet av det hårdare segrade ytsmältskiktet (SLS) på SSM-gjutytan uppvisar SSM-gjutgodset bättre böjningsutmattningsegenskaper än högtryckspressgjutprover (HPDC). Vidare, i jämförelse med standard SSM-processen, visar gjutgods med intensiv omrörning liknande men mer tillförlitliga utmattningsegenskaper. Detta kan tillskrivas elimineringen av de stora inre porerna genom intensiv omrörning. Dessutom, på grund av gradientspänningsfördelningen i böjbelastningen, spelar ytdefekterna en betydande roll för utmattningsegenskaperna. Med ökningen av provernas tjocklek förändrades felmekanismerna.

Krympporerna i testet med reducerat tryck (RPT) spelar en betydande roll för noggrannheten av smältkvalitetsbedömningen. För RPT-prover utan signifikanta krympningsporer observeras en god korrelation mellan bifilmindex (BI)/densitetsindex (DI) och vätehalt. Dessutom är korrelationen mellan BI och förlängning också starkt påverkad av förekomsten av kluster av krympningsporer. Detta kan tillskrivas konflikten mellan definitionen av BI och påverkan av kluster av krympningsporer på duktiliteten. Baserat på detta föreslog vi en optimerad BI där klustren av krympningsporer behandlades som enstaka porer, vilket ökade tillförlitligheten av korrelationen mellan BI och förlängning. 

 

Place, publisher, year, edition, pages
Jönköping: Jönköping University, School of Engineering, 2023. p. 75
Series
JTH Dissertation Series ; 085
Keywords
Rheometal™ process, aluminum alloys, stirring, segregation, porosity, oxides, ductility, fatigue performance, melt quality
National Category
Metallurgy and Metallic Materials
Identifiers
urn:nbn:se:hj:diva-62912 (URN)978-91-89785-03-8 (ISBN)978-91-89785-04-5 (ISBN)
Public defence
2023-12-08, E1405 (Gjuterisalen), Tekniska Högskolan, Jönköping, 09:00 (Swedish)
Opponent
Supervisors
Available from: 2023-11-22 Created: 2023-11-22 Last updated: 2023-11-22Bibliographically approved

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Zhang, QingDahle, ArneJarfors, Anders E.W.

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