The relation among process parameters, rheological properties, and the solid fraction of the slurry produced during a Rheo-Metal process for Al-Si alloys is not yet fully understood and contradictory data are available in the literature. There are numerous models that describe the evolution of the rheological properties of a semi-solid material as a function of temperature, applied stresses, and time, which are often based on significant approximations. The Ostwald-de-Waele model, which is the simplest one, assumes viscosity as a function of the shear rate and fluids, whose behaviour is time-independent, whereas the Cross model considers that, at extreme boundary conditions (i.e. at the very low or very high shear rate) thixotropic fluids assume a Newtonian viscosity. The Herschel-Bulkley model is a generalization of the Bingham plastic model and describes the flow of viscoplastic fluids, which exhibit solid behaviour below a certain threshold of yield stress (0) and flow, with linear (Bingham body) or non-linear (Herschel-Bulkley) behaviour, above 0. However, none of these models allows to exhaustively describe simultaneously the behaviour of the slurry in short-term experiments and at the steady state. The static yield strength becomes significantly more dominant with the increase of the solid fraction, until, for values below approximately 0.65 (i.e. at the maximum packaging of the solid particles), the slurry could be treated as a “porous solid body”. So, to model the relation between deformation and stress the use of approaches of continuum mechanics are necessary.
In this study, we developed a model that allows to predict the characteristics of the slurry, using data obtained by a torquemeter connected to the cold solid stirring materials (EEMs) used in rheo-metal processes for slurry preparation. We have studied an AlSi4 and an AlSi7 alloys, preparing the slurries using three different EEMs sizes (5%, 7%, 8% of the total weight of cast) and various rotation speeds of the rod (900 rpm, 1100 rpm, 1200 rpm). To reduce uncertainty factors and to simplify the interpretation of results, we used the same stirring time for each batch on the same alloy, we monitored the actual rotation speed for each sample with a tachometer, and a thermocouple was used to ensure the same initial temperature for the preparation of the semi-solid. The obtained slurries were used to produce tensile test specimens, using a High Pressure Die Casting press. A portion of the specimens was cut, embedded in resin, and prepared for micrographic analyses. These samples were treated with Weck's reagent (4 g KMnO4 and 1 g NaOH in 95 mL distilled water), a colour etching technique aimed at revealing the Si distribution in the cross-section of the -Al particles and distinguishing the solid fraction coming from the slurry from that formed during quenching. The images obtained with the optical microscope were processed using ImageJ processing software. A grid method was applied to calculate the percentage ratio between the number of intersections that fell on the dark and lighter areas of the -Al particles.
Dark areas observed in micrographs correspond to pure Al and were already solid in the slurry, before quenching, while the light areas, containing a higher content of Si, were liquid in the slurry and solidified during quenching. The experimental results evidenced a correlation between the solid fraction and the viscosity of the slurry and a dependence on the size of the EEM used during preparation, especially for the AlSi4 alloy. A good overlap of the data is observed combining the experimental data obtained for the two alloys. Furthermore, a progressive decrease in the dispersion of viscosity values was observed as the solid fraction of the slurry decreased, indicating a system slightly controlled by the interaction between the solid particles. The performed micrographic analysis showed average particle sizes and shape factor values quite dispersed, that fell within the measurement uncertainty. Therefore, these parameters did not explain the observed differences.
Finally, mechanical tests were carried out on the tensile specimens to seek a correlation between the viscosity and solid fraction of the slurry and the mechanical properties of the die-cast components. The study showed a general improvement in the mechanical properties of the specimens as the solid fraction increased, but requires further investigation to reduce the contribution due to the defects present in the component.